離子液體 [BMIm]OTf 1-丁基-3-甲基咪唑三氟甲磺酸鹽

Synonym BMIMOTfProduct Category Ionic LiquidsCAS Number 174899-66-2Chemical Name 1-Butyl-3-methylimidazolium trifluoromethanesulfonateMolecular Formul

Synonym   BMIMOTf
Product Category  Ionic Liquids
CAS Number  174899-66-2
Chemical Name  1-Butyl-3-methylimidazolium trifluoromethanesulfonate
Molecular Formula  C9H15F3N2O3S
Molecular Weight  288.29
Assay   ≥98%(HPLC)
Appearance  Colorless to Yellow Liquid
Melting Point  -15°C
Packaging  50g,100g,250g,500g and 1kg
Storage   Store at room temperature

1-Butyl-3-methylimidazolium trifluoromethanesulfonate (also named as BMIMOTf) is a versatile ionic liquid commonly used in synthetic chemistry. It can also act as a promoter for the room temperature glycosylation of both thiophenyl and trichloroacetimidate glycoside donors.
[bmim][OTf] as co-solvent/promoter in room temperature reactivity-based one-pot glycosylation reactions. [1]
Selective Quenching of 2-Naphtholate Fluorescence by Imidazolium Ionic Liquids. [2]
A new application of Baylis–Hillman alcohols to a diastereoselective synthesis of 3-nitrothietanes. [3]
A study of new anhydrous, conducting membranes based on composites of aprotic ionic liquid and cross-linked SPEEK for fuel cell application. [4]
References:
[1] M.Carmen Galan, et al, Chem. Commun., 2010, 46(12), pp 2106-2108.
[2] V.Kumar, et al, J. Phys. Chem. B, 2012, 116(39), pp 12030-12037.
[3] A.Rai, et al, Tetrahedron, 2012, 68(11), pp 2459-2464.
[4] R.S.Malik, et al, Electrochim Acta, 2015, 152, pp 352-359.

標簽: 離子液體 [BMIm]OTf 1-丁基-3-甲基咪唑三氟甲磺酸鹽